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Welcome back to the forum and hope you find this resourceful.
If you were looking for the arrow to change the email address in the card file, I can't see that possible however, you can highlight the supplier whom you would like to send the Remittance Advice then enter the email address under "To Be Emailed " section.
If the email address that is picked from the card is different you can also change it as you go but it will not update the card file. To update the card file you will need to click on the arrow then click on the arrow next to the supplier name when it opens the "Pay Bills" window to go to the card file.
Hope this helps and let us know how you go as we are happy to help further.